--- title: Thermodynamics, Scattered date: 2024-11-10 --- # A Couple of Equations When it comes to energy transfer and phase changes there are only two useful equations. 1. **Specific Heat Equation**: This equation is used to calculate the heat required to change the temperature of a substance without a phase change. $$ \Delta \textbf{KE}=Q = mc\Delta T $$ - $Q$ = heat energy added or removed (in joules, J) - $m$ = mass of the substance (in kilograms, kg) - $c$ = specific heat capacity of the substance (in J/kg°C) - $\Delta T$ = change in temperature (in °C or K) 2. **Latent Heat (Potential Energy Buildup)**: This equation is used for phase changes, where energy changes the state of the substance (like melting or boiling) without changing its temperature. $$ \Delta \textbf{PE} = Q = mL $$ - \( Q \) = heat energy added or removed (in joules, J) - \( m \) = mass of the substance (in kilograms, kg) - \( L \) = latent heat of the substance (in J/kg), which could be the latent heat of fusion (for melting/freezing) or vaporization (for boiling/condensing) These equations together describe the heat energy required for changing the temperature of a substance and for changing its phase. **It is important to note the alternate arrangement of both: $$ Q=nc_{\mathrm{mol}}\Delta T = \Delta \textbf{KE} $$ or for the other Latent Heat equation: $$ \Delta \textbf{PE} = Q = nL_{\mathrm{mol}} $$ - $n$ is the number of moles - the subscript `mol` notates the same variable, but in units *per* mole. - ==You might see both==, at least they were both on the concept builders. # Black-body radiation All objects/bodies emit electromagnetic radiation over a range of wavelengths. Cooler objects emit less radiation than warmer bodies, simply because of having less energy. An increase in temperature directly correlates with a smaller wavelength ($\lambda$), and a higher frequency ($f$ or $v$). Radiation being *incident* means that it strikes or falls upon a surface, object, or body. Radiation that is incident on an object is partially absorbed and partially reflected. **Thermodynamic Equilibrium** is a state in which a body emits radiation at the same rate that radiation hits it. Therefore, a good absorber of radiation is also a good emitter. A perfect absorber absorbs all E.M. radiation incident on it. Such an object is called a *black body*. This doesn't mean no energy is emitted, however. A black body remits the radiation it absorbs as a thermal radiation in a spectrum determined solely by its temperature. The intensity of the remissions of a black body is given by a function defined so: $$ I(\lambda,T) $$ Where $I$ is the *power* intensity that is radiated per unit of wavelength $\lambda$, per unit area of the black body. By multiplying the differential of $\lambda$: $$ I(\lambda, T)\mathrm{d}\lambda $$ Provides the power per unit area of the black body, from the interval $\left[\lambda, \lambda + \mathrm{d}\lambda\right]$, given that $\mathrm{d}\lambda$ is an infinitesimally small quantity.